Conversion of glucose into 5-hydroxymethylfurfural in different solvents and catalysts: Reaction kinetics and mechanism

Abstract

Synthesis of 5-hydroxymethylfurfural (HMF) from glucose was done in H 2 O, dimethylsulfoxide (DMSO) and 1-butyl-3-methylimidazolium chloride ([Bmim]Cl) catalyzed by metal (III) chloride (FeCl 3 ·6H 2 O, CrCl 3 ·6H 2 O and AlCl 3 ). The effects of solvent/catalyst system and temperature/time on the performance of the reaction are studied. HMF yield in the different solvents follows a decreasing order as DMSO > [Bmim]Cl > H 2 O. The highest HMF yield is achieved by CrCl 3 ·6H 2 O, followed by AlCl 3 and then FeCl 3 ·6H 2 O. An optimal temperature/time is found at 393 K or 403 K and a time between 30 min and 480 min. Under the optimal reaction conditions, HMF yields of 54.43% and 52.86% are obtained in DMSO with CrCl 3 ·6H 2 O at 403 K and 480 min and AlCl 3 at 393 K and 240 min, respectively. The mechanism of the halide chlorides catalyzed glucose conversion reaction is proposed. The kinetic model is established to describe the HMF formation and the experimental data conform to the model.